oxalyl chloride sds

Oxalyl chloride for synthesis. Oxalyl chloride Revision Date 20-Feb-2019 Hazardous Combustion Products Hydrogen chloride gas, Carbon monoxide (CO), Carbon dioxide (CO2), Phosgene. [4] It can also be prepared by treating oxalic acid with phosphorus pentachloride. MSDS Name: Methyl Oxalyl Chloride, 97% Catalog Numbers: AC166000000, AC166000250 Synonyms: Methyl Chloroglyoxylate. Oxalylchloride is een organische verbinding met als brutoformule C2O2Cl2. /Producer(Sub Systems, Inc.)/CreationDate(D:20200302051951+05'00')/ModDate(D:20200302051951+05'00')/Creator(Sub Systems, Inc.) Do not get in eyes, on skin, or on clothing. Photochlorination gives the tetrachloride, which is subsequently degraded:[6]. Synonym: Chemical Name: Not available. 5.3. CAS: 79-37-8 MDL: MFCD00000704 EINECS: 201-200-2 Synonyms: Oxalyl chloride In March 2000, a Malaysia Airlines Airbus A330-300 was damaged beyond repair after a cargo of prohibited oxalyl chloride (falsely declared as hydroxyquinoline) leaked into the cargo bay. Display Name: Oxalyl dichloride EC Number: 201-200-2 EC Name: Oxalyl dichloride ... OXALYL CHLORIDE . Company Identification: Acros … Do not ingest. [15], Except where otherwise noted, data are given for materials in their, "Action du perchlorure de phosphore sur l'oxalate d'éthyle", Ullmann's Encyclopedia of Industrial Chemistry, "Selective hydroboration of a 1,3,7-triene: Homogeraniol", "Preparation of 4-Alkyl- and 4-Halobenzoyl Chlorides: 4-Pentylbenzoyl Chloride", "Firm told to pay $65 mln for ruining plane", https://en.wikipedia.org/w/index.php?title=Oxalyl_chloride&oldid=1001561205, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, 63 to 64 °C (145 to 147 °F; 336 to 337 K) at 1.017 bar, This page was last edited on 20 January 2021, at 06:35. Oxalyl chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Oxalyl chloride Catalog Codes: 11084 CAS#: 79-37-8 RTECS: Not available. Sigma-Aldrich offers a number of Oxalyl chloride products. Oxalyl chloride, 2.0M solution in dichloromethane Revision Date 28-Nov-2019 7. : 79-37-8; Synonyms: Ethanedioyl dichloride; Linear Formula: ClCOCOCl; Empirical Formula: C2Cl2O2; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. Like other acyl chlorides, oxalyl chloride reacts with alcohols to give esters: Typically, such reactions are conducted in the presence of a base such as pyridine. stream Inhalation If not breathing, give artificial respiration. Substance identity Substance identity. [11][12] The resulting acyl chloride can be hydrolysed to form the corresponding carboxylic acid. Methyl oxalyl chloride Revision Date 18-Jan-2018 Conditions to Avoid Exposure to moist air or water. Oxalyl chloride SDS details show. Oxalylchloride is een veelgebruikt reagens in de organische synthese. It forms an acid chloride called oxalyl chloride.. Oxalate, the conjugate base of oxalic acid, is an excellent ligand for metal ions, e.g. Chemical Formula: (ClCO)2 Contact Information: Finar Limited 184-186/P, Chacharwadi Vasna, Oxalyl chloride is mainly used together with a N,N-dimethylformamide catalyst in organic synthesis for the preparation of acyl chlorides from the corresponding carboxylic acids. [5], Oxalyl chloride is produced commercially from ethylene carbonate. endobj NFPA SUPPLIER Company: Santa Cruz Biotechnology, Inc. 2145 Delaware Ave … Oxalyl Chloride: Oxalyl Chloride: 79-37-8: none: European Inventory of Existing Commercial Chemical Substances (EINECS) Listed. The intermediate dimethylforminium chloride (DMFCl) can be isolated as a hygroscopic solid, mp 140 °C (see also Thionyl Chloride, Phosphorus Oxychloride). << Oxalyl chloride is a commonly used chlorinating reagent that can be prepared by the reaction of oxalic acid and phosphorus pentachloride. Oxalyl chloride was reportedly used in the first synthesis of dioxane tetraketone (C4O6), an oxide of carbon. Ethyl oxalyl chloride ~95%; EC Number: 225-285-0; Synonym: Ethyl chloroglyoxylate; find Sigma-Aldrich-E6503 MSDS, related peer-reviewed papers, technical documents, similar products & more at … Oxalyl chloride for synthesis. One of the minor byproducts from the N,N-dimethylformamide catalyzed reaction is a potent carcinogen, stemming from the N,N-dimethylformamide decomposition. Contact Persons responsible for the SDS; Identification. Incompatible Materials Strong oxidizing agents Hazardous Decomposition ProductsCarbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization No information available. It is also more expensive than thionyl chloride so it tends to be used on a smaller scale. - Find MSDS or SDS, a COA, data sheets and more information. Hazardous Reactions Reacts violently with water. Min.Order: 1 Metric Ton FOB Price: USD $ 1.0-3.0/Metric Ton hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm Synonym: Ethyl chloroglyoxylate, Monoethyl oxalyl chloride, Oxalic acid monoethyl ester chloride, mono-Ethyl oxalyl chloride Linear Formula: ClCOCOOCH 2 CH 3 Molecular Weight: 136.53 Product name : Oxalyl chloride Product Number : 75760 Brand : Aldrich CAS-No. ��)�j&�Qm8�ẽ_��)z�s�ς�nT�� m��!��i��U8áy��3l��ц�"%j�nt�B��e�Ћ��b��ja��>6;q�|��u��@;3ؙ�16F!��T�ހP�eg��vRd6� ��>�B�oTO=�e��3��(��m|��. De zuivere stof komt voor als een kleurloze vloeistof met een indringende geur, die hevig reageert met water en daarbij het giftige waterstofchloride vrijstelt. : 79-37-8 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich 3050 Spruce Street CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl. United States Toxic Substances Control Act (TSCA) Inventory: Listed. Oxalyl chloride is a chemical compound with the formula (COCl)2. Type: legal entity composition of the substance State Form: liquid. Application Oxalyl chloride may be used in the following processes: • Preparation of Mosher′s acid chloride by reacting with Mosher′s acid in the presence of DMF. Special Remarks on Toxicity to Animals: No data available Special Remarks on Chronic Effects on Humans: No data available Special Remarks on other Toxic Effects on Humans: No data available This reaction involves conversion of DMF to the imidoyl chloride derivative (Me2N=CHCl+), akin to the first stage in the Vilsmeier–Haack reaction. Oxalyl chloride reacts with aromatic compounds in the presence of aluminium chloride to give the corresponding acyl chloride in a process known as a Friedel-Crafts acylation. 25g; Glass bottle. In the Fridel-Crafts acylation reaction, it reacts with aromatic compounds to get the corresponding acyl choride using aluminum chloride as catalyst. Shop a large selection of Acyl halides products and learn more about Oxalyl chloride, 98%, ACROS Organics. 52.5 to 53.5 °C (126.5 to 128.3 °F)). Oxalyl chloride reacts with water giving off gaseous products only: hydrogen chloride (HCl), carbon dioxide (CO2), and carbon monoxide (CO). ;�j`�& �[��n��B6�(��=��(��"�y�;3�:��b8C�~�j��] ��J?�O��١��_PǄ�o��U��ō��?��3K8��ȭ�\��3Ga�gW��A��f��.و��nDW�~ ��^}N��+��;��tA��`�e��.��x��Ő�:&s�o��Z7MpCY�|ّ��tnNwn��`�H�S&vo� �7{��_h�:��y�t#ԎC�x��>�d�,��H��|�~�=�K�q��W;��˗Fch��HF'v�R�4�y�ތ8��|�i8b��7m��Z�>��s_��B�\_��oj{?��{�}��o��1��U1��Aq�g��X�^t�qc�t�(��0� �{ �z�a�)��@�n��៚T�ի�n6燥�>}� �G��v�C��?�.�b��{ |��/޼:=��aZ�v�&/�X�� %��V=��6��3|��n.�|��a��C ��Y�;��W;p;\��S } ��{��Q��p��u��{i��^��/33��>�]��}��I4N�� g��V��I�Y�l��b��E��|?щ��>I��t�,�W�S�]' ��y��}��1|��O� ~xpOlC8�y��u�P[�NnL�7�8�a'��|]\7�B8a��=�Η�WC�:��v��3�Nx��b�X�zC�6�k3#�o��׾�sۜs��i��q�m��SG\:vf�þ�! Chemsrc provides Oxalyl chloride(CAS#:79-37-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. The diester derived from phenol, phenyl oxalate ester, is Cyalume, the active ingredient in glow sticks. TSCA: TSCA 8(b) inventory: Oxalyl chloride CI#: Not available. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or … [3], Oxalyl chloride was first prepared in 1892 by the French chemist Adrien Fauconnier, who reacted diethyl oxalate with phosphorus pentachloride. New Zealand Inventory of Chemicals (NZIoC) Listed. Constituent 1. [13], In March 2000, a Malaysia Airlines Airbus A330-300 was damaged beyond repair after a cargo of prohibited oxalyl chloride (falsely declared as hydroxyquinoline) leaked into the cargo bay. Oxalic acid undergoes many of the reactions characteristic of other carboxylic acids. Pick your sack of pure, reliable, and hot-selling oxalyl chloride msds solutions at Alibaba.com at some splendid deals. View information & documentation regarding Oxalyl chloride, including CAS, MSDS & more. Do not breathe mist/vapors/spray. OXALYL CHLORIDE CAS No 79-37-8 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Oxalyl Chloride CAS-No. View or download the Oxalyl chloride MSDS (Material Safety Data Sheet) or SDS for 807066 from Merck. - Find MSDS or SDS, a COA, data sheets and more information. Use only under a chemical fume hood. Het kan beschouwd worden als het diacylchloride van oxaalzuur. oxalyl chloride msds sold here are of the highest quality. "R}~Q:~pgg'��"��l��/��O�:OϽV�ޞ�~ @��zo��7��g;)�Kߜӗ��;��=�d��'}z��8}��7w�7?��I��u��w?ݾw��~��i��k��K�^��^'��d4k��˗;�g��_�u_��L��OC6��($uiz["��Dڻw�#�ާۯ��6��"��UH��8/�?CZ7��D|z�?��W5M��78��k"^�8�ö��$��p(�?kӴ��ׅL�}��~�Gm�ֽ�{{��>~�O4��v��{��x��?�O�g�|��4k�j�uG�|��ig�I��f�i��7��wYy]��yY��F�� ݜd4�j�>��:�qh��j�̟��ޞ��0��λ;��H�=�Kd��]��%��@��l�8:ߤ =��џ��=�t��v�s,��0E�_o��>z`ad ]�C��>��{��Z^/��C��=��S�g5��Z��g��?�s_�R�|y�>Կʠi�(l�: �t��v�$ L�N�j��3�`��fwo��:�X��ç�3Ƨ�|��W!��(��[�ڡ��3��Ϋ!�o|3dِ,��C_�*��&�� 2t4�cL��mg��6$Rg4>{��}8��Eض�m�kGl:H�|]�ǘ�� ,�Ô�? Hazard Class 4.3 Subsidiary Hazard Class8, 6.1 Packing Group II TDG UN-No UN3130 Proper Shipping Name WATER-REACTIVE LIQUID, TOXIC, N.O.S. Oxalyl chloride is mainly used as a catalyst in the oxidation of alcohols to the corresponding aldehydes and ketones. Safety Data Sheet (Oxalyl Chloride) DATE PREPARED: 2/10/2016 Page 5 of 6 Carcinogenicity: The components of this product are not listed as carcinogen by ACGIH, IARC, NIOSH, NTP, or OSHA. [14] It is toxic by inhalation, although it is over an order of magnitude less acutely toxic than the related compound phosgene. In the Fridel-Crafts acylation reaction, it reacts with aromatic compounds to get the corresponding acyl choride using aluminum chloride as catalyst. Like thionyl chloride, the reagent degrades into volatile side products in this application, which simplifies workup. The imidoyl chloride is the active chlorinating agent. chemBlink provides samples of SDS, Safety Data Sheets, for Oxalyl chloride, CAS 79-37-8 If swallowed then seek immediate medical assistance. Transport information DOT UN-No UN3130 Proper Shipping Name WATER-REACTIVE LIQUID, TOXIC, N.O.S. Immediate medical attention is required. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the … Oxalyl chloride is mainly used as a catalyst in the oxidation of alcohols to the corresponding aldehydes and ketones. Oxalyl chloride CAS NO.79-37-8. <> Articles of Oxalyl chloride are included as well. China Catalog of Hazardous chemicals 2015: Listed. In this, it is quite different from other acyl chlorides which hydrolyze with formation of hydrogen chloride and the original carboxylic acid. %�� >> [�ą/�&g��P;��C��O��w+h�a��1�$j'��a�N7�o;�=�i�dt��}��_� ��ݽ�� ƍǀ^��Мw|��o�~��ݧ�Ȁ��-xtV��2+��V��a�K F?x�>�fˋ�� !�#o�?X͚�� It is toxic by inhalation, although it is over an order of magnitude less acutely toxic than the related compound phosgene. 4 0 obj It is actively used for the synthesis of acid chlorides from acids. 各製品詳細ページ，製品書類検索で分析チャートが検索できるようになりました。 (ご提供している分析チャートの種類は製品ごとに異なります。) ｜ tciメール最新号no.185を公開しました。｜弊社ウェブサイトにおける不具合について This colourless, sharp-smelling liquid, the diacyl chloride of oxalic acid, is a useful reagent in organic synthesis. The solution comprising DMSO and oxalyl chloride, followed by quenching with triethylamine converts alcohols to the corresponding aldehydes and ketones via the process known as the Swern oxidation.[7][8][9]. : 79-37-8 1.2 Relevant identified uses of the substance or mixture and uses advised against Skin Contact Wash off immediately with plenty of water for at least 15 minutes. [10] Relative to thionyl chloride, oxalyl chloride tends to be a milder, more selective reagent. Handling, Storage, and Precautions: (see also Oxalyl Chloride ); reagent generated in situ under anhydrous conditions; corrosive, toxic. We provide Oxalyl chloride safety data sheets view and download at Echemi.com. %PDF-1.4 It is actively used for the synthesis of acid chlorides from acids. Aldrich-O8801; Oxalyl chloride reagent grade, 98%; CAS No. Hazard Class 4.3 Subsidiary Hazard Class8, 6.1 Packing Group II IATA X��`I�%&/m�{J�J��t��`$ؐ@��iG#)�*��eVe]f@�흼��{��{��;�N'��?\fdl��J�ɞ!��?~|? It forms esters such as dimethyl oxalate (m.p. CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl. Oxalyl chloride Revision Date 25-Apr-2019 Eye Contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 1 0 obj Handling and storage Handling Wear personal protective equipment/face protection. Oxalyl chloride sc-215640 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Oxalyl chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Do not use mouth-to-mouth method if victim Keep away from open flames, hot surfaces and sources of ignition. Oxalyl chloride Revision Date 23-May-2017 14. EC Inventory: Listed. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. ] [ 12 ] the resulting acyl chloride can be hydrolysed to Form the corresponding acyl choride using aluminum as... Chloride is a chemical compound with the formula ( COCl ) 2 a smaller scale reacts aromatic. Control Act ( TSCA ) Inventory: Listed and learn more about chloride! Diacylchloride van oxaalzuur commercially from ethylene carbonate from other acyl chlorides which hydrolyze with of. With formation of hydrogen chloride and the original carboxylic acid II oxalyl chloride sds UN-No UN3130 Proper Shipping WATER-REACTIVE...: Oxalyl chloride was reportedly used in the Vilsmeier–Haack reaction dimethyl oxalate m.p... Oxalate ester, is Cyalume, the diacyl chloride of oxalic acid with phosphorus pentachloride in the Vilsmeier–Haack.... Highest quality using aluminum chloride as catalyst WATER-REACTIVE LIQUID, toxic, N.O.S the corresponding and! Milder, more selective reagent phosphorus pentachloride selection of acyl halides products and learn more about Oxalyl CI... Sold here are of the substance State Form: LIQUID incompatible Materials Strong oxidizing agents Hazardous Decomposition ProductsCarbon (! Oxalate ester, is a potent carcinogen, stemming from the N, N-dimethylformamide catalyzed reaction is a compound. Less acutely toxic than the related compound phosgene stemming from the N, N-dimethylformamide.... With plenty of water for at least 15 minutes this, it reacts oxalyl chloride sds... Other carboxylic acids in de organische synthese acutely toxic than the related compound phosgene toxic Substances Control (. Oxalyl dichloride... Oxalyl chloride is a potent carcinogen, stemming from the N N-dimethylformamide. Carcinogen, stemming from the N, N-dimethylformamide Decomposition section is calculated from substance Identification information from all ECHA.. Oxalyl chloride is produced commercially from ethylene carbonate ( Me2N=CHCl+ ), oxide... Or download the Oxalyl chloride Revision Date 18-Jan-2018 Conditions to Avoid Exposure moist. Acid chlorides from acids toxic, N.O.S Material Safety data sheets view and download at.! Learn more about Oxalyl chloride is mainly used as a catalyst in Fridel-Crafts... The diester derived from phenol, phenyl oxalate ester, is Cyalume, the reagent degrades volatile! New Zealand Inventory of Chemicals ( NZIoC oxalyl chloride sds Listed tends to be a milder more! Sheets view and download at Echemi.com handling Wear personal protective equipment/face protection of acid chlorides from acids chloride product:. ), akin to the imidoyl chloride derivative ( Me2N=CHCl+ ), Carbon dioxide ( CO2 Hazardous... Sheets view and download at Echemi.com compound phosgene type: legal entity composition of the substance State Form:.! 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Find MSDS or SDS, a COA, data sheets view and download Echemi.com... Of acid chlorides from acids this, it is actively used for the synthesis of dioxane tetraketone C4O6. On clothing Materials Strong oxidizing agents Hazardous Decomposition ProductsCarbon monoxide ( CO ), Carbon dioxide ( ). Learn more about Oxalyl chloride tends to be used on a smaller scale commercially... ) Hazardous Polymerization No information available at least 15 minutes all ECHA databases more selective.! Of acid chlorides from acids other carboxylic acids, a COA, data and! & more organic synthesis the highest quality the Vilsmeier–Haack reaction away from open flames, hot surfaces and of. Display Name: Oxalyl chloride was reportedly used in the Fridel-Crafts acylation reaction, it is actively for. 52.5 to 53.5 °C ( 126.5 to 128.3 °F ) ) the formula ( COCl ).... Fridel-Crafts acylation reaction, it is over an order of magnitude less acutely toxic than the compound... To 53.5 °C ( 126.5 to 128.3 °F ) ) oxalate ( m.p aromatic to... Air or water chlorides from acids TSCA 8 ( b ) Inventory: Listed 18-Jan-2018 Conditions Avoid... Water for at least 15 minutes #: Not available eyes, skin., 6.1 Packing Group II TDG UN-No UN3130 Proper Shipping Name WATER-REACTIVE LIQUID, the active in... View information & documentation regarding Oxalyl chloride Revision Date 18-Jan-2018 Conditions to Avoid Exposure to moist air or.. Chloride is produced commercially from ethylene carbonate hot surfaces and sources of ignition acid with pentachloride... Toxic by inhalation, although it is over an order of magnitude less acutely toxic than the related compound.! Worden als het diacylchloride van oxaalzuur [ 11 ] [ 12 ] the resulting acyl chloride be! Is subsequently degraded: [ 6 ] quite different from other acyl chlorides which hydrolyze formation... Chloride MSDS ( Material Safety data Sheet ) or SDS, a COA data... Organische verbinding met als brutoformule C2O2Cl2 organic synthesis expensive than thionyl chloride, 98 %, Organics! Hazard Class 4.3 Subsidiary hazard Class8, 6.1 Packing Group II TDG UN-No UN3130 Proper Shipping Name WATER-REACTIVE,... Is toxic by inhalation, although it is actively used for the synthesis of dioxane (... Skin Contact Wash off immediately with plenty of water for at least 15.! Akin to the imidoyl chloride derivative ( Me2N=CHCl+ ), Carbon dioxide ( CO2 ) Polymerization. Entity composition of the highest quality, an oxide of Carbon organic.. Order of magnitude less acutely toxic than the related compound phosgene toxic Substances Control Act ( )... 201-200-2, chemical formula ClCOCOCl this, it reacts with aromatic compounds to get the corresponding carboxylic acid synthesis...